Interconnect structure and methods of making same

ABSTRACT

A method of manufacturing a semiconductor interconnect structure may include forming a low-k dielectric layer over a substrate and forming an opening in the low-k dielectric layer, where the opening exposes a portion of the substrate. The method may also include filling the opening with a copper alloy and forming a copper-containing layer over the copper alloy and the low-k dielectric layer. An etch rate of the copper-containing layer may be greater than an etch rate of the copper alloy. The method may additionally include patterning the copper-containing layer to form interconnect features over the low-k dielectric layer and the copper alloy.

PRIORITY CLAIM AND CROSS-REFERENCE

The present application claims priority to and is a continuation of U.S. patent application Ser. No. 13/791,352, filed on Mar. 8, 2013, and entitled “Interconnect Structure and Methods of Making Same,” which application is incorporated herein by reference.

BACKGROUND

Since the mid-1990's so-called damascene processes have been the dominant technology for forming conductive interconnects in integrated circuits. Those skilled in the art recognize that damascene processing involves forming openings (via and trenches) in a dielectric layer and then filling the openings with a conductive, typically copper. The copper is typically deposited by initially depositing a thin seed layer within the openings and then filling the openings by electroplating copper.

FIG. 1 is a cross-sectional view of an interconnect formed on a semiconductor device from the prior art. In the figure, a patterned dielectric layer 54 is formed on a substrate 50. Formed between an opening of the patterned dielectric layer 54 and thereabove is a conductive layer 58. Formed between the dielectric layer 54 and the conductive layer 58 is a hard mask 56. A mask layer, such as a tri-layer photoresist layer 60 is formed above the conductive layer 58. In a later process, using the tri-layer photoresist layer 60 as a mask, the conductive layer 58 will be etched to form conductive lines 58 above the dielectric layer 54, as shown in FIG. 2.

The conventional copper metal line formation method can have a number of problems. One problem may be misalignment. In the process of device feature or pattern exposure, the alignment between successive layers that are being created is of critical importance. Smaller device dimensions place even more stringent requirements on the accuracy of the alignment of the successive layers that are superimposed on each other. In FIG. 2, following the etching of the conductive layer 58 in which the photoresist layer 60 is used as a mask to form conductive lines 58, via recesses VR may be formed at the juncture of a conductive line 58 and the hard mask 56 and/or the dielectric layer 54. Via recesses can be caused when the photoresist layer is misaligned (e.g., shifted to one side). Such misalignment can result from a mask misalignment failure, for example, during the photolithography process. Due to this misalignment, the via recess formed can be a serious problem in the conventional copper etch approach by causing unstable yield and decreased reliability.

BRIEF DESCRIPTION OF DRAWINGS

Embodiments of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.

FIGS. 1 and 2 are cross-sectional views of a part of an interconnect structure of a semiconductor device from the prior art;

FIG. 3 is a flowchart of a method of fabricating an interconnect structure of a semiconductor device according to various embodiments of the present disclosure;

FIGS. 4-10 are diagrammatic fragmentary cross-sectional side views of a portion of a wafer at various stages of fabrication in accordance with various embodiments of the present disclosure; and

FIG. 11 is a chart showing different etch rates of copper alloy and pure copper at different annealing conditions.

DETAILED DESCRIPTION

In the following description, specific details are set forth to provide a thorough understanding of embodiments of the present disclosure. However, one having ordinary skill in the art will recognize that embodiments of the disclosure can be practiced without these specific details. In some instances, well-known structures and processes are not described in detail to avoid unnecessarily obscuring embodiments of the present disclosure.

Embodiments will be described with respect to a specific context, namely an interconnect structure for an integrated circuit. Other embodiments may also be applied, however, to other semiconductor devices and features. For instance, the present teachings could be applied to structures other than an integrated circuit, such as an interposer device, a printed circuit board, a package substrate, and the like.

With reference now to FIG. 3, there is shown a flowchart of a method 2 for fabricating an interconnect structure of a semiconductor device according to various aspects of the present disclosure. Referring to FIG. 3, the method 2 includes block 4, in which a dielectric layer is formed on a substrate. The method 2 includes block 6, in which the dielectric layer is patterned to form an opening therein. The method 2 includes block 8, in which the opening is filled and the dielectric layer is covered with a metal layer having a first etch rate. The method 2 includes block 10, in which the metal layer is planarized so that the metal layer is co-planar with the top of the dielectric layer. It will be understood that when relative terms such as first etch rate, second etch rate, lower etch rate, etc., are used in the present disclosure, these terms are used to describe the etch characteristics of the material when exposed to a same etch process. In other words, the material etch rate prior to, e.g., annealing, when exposed to a given etch process is higher than the same materials etch rate, after annealing, when exposed to the same or a similar etch process. The method 2 includes block 12, in which the metal layer is annealed to change the first etch rate to a second etch rate, the second etch rate being lower than the first etch rate. The method 2 includes block 14, in which a copper-containing layer is formed over the annealed metal layer and the dielectric layer. The copper-containing layer has an etch rate greater than the second etch rate of the annealed metal layer. The method 2 includes block 16, in which the copper-containing layer is etched to form interconnect features. The etching stops at the top of the annealed metal layer and does not etch into the underlying annealed metal layer.

It is understood that additional processes may be performed before, during, or after the blocks 4-16 shown in FIG. 3 to complete the fabrication of the semiconductor device, but these additional processes are not discussed herein in detail for the sake of simplicity.

FIGS. 4-10 are diagrammatic fragmentary cross-sectional side views of a portion of a wafer at various fabrication stages according to embodiments of the method 2 of FIG. 3. It is understood that FIGS. 4-10 have been simplified for a better understanding of the inventive concepts of the present disclosure. It should be appreciated that the materials, geometries, dimensions, structures, and process parameters described herein are exemplary only, and are not intended to be, and should not be construed to be, limiting to the invention claimed herein. Many alternatives and modifications will be apparent to those skilled in the art, once informed by the present disclosure.

With reference now to FIG. 4, there is shown an illustrative semiconductor structure 100 shown in highly simplified cross-sectional views. Various features not necessary for understanding of the invention have been omitted for sake of clarity and brevity. Semiconductor structure 100 includes a substrate 110 upon which has been formed an etch stop layer 120. Substrate 110 refers generally to any structures or materials underlying etch stop layer 120. In some applications, substrate 110 includes a semiconductor wafer such as a bulk silicon wafer or a silicon (or other semiconductor material) layer formed atop a bulk wafer and separated therefrom by, e.g., a buried oxide layer in a so-called silicon on insulator (SOI) arrangement. One or more active or passive devices, such as transistors or capacitors, could be formed in substrate 110. In another application, substrate 110 could be an underlying metal (or other conductor) layer in a multi-metal interconnect scheme. For instance, substrate 110 could be an underlying metal layer (or several stacked metal layers) manufactured according to the steps illustrated in FIGS. 4-10.

A dielectric layer 130, preferably a low-k dielectric layer 130 is formed on the etch stop layer 120. Low k generally refers to a dielectric layer having a dielectric constant of less than about 3.5. Materials such as porous silicon oxide, doped silicon oxide, silicon carbide, silicon oxynitride, and the like could be employed for dielectric layer 130, although these are examples only and are not intended to be exhaustive or limiting. The dielectric layer 130 may be formed on the etch stop layer 120 by a process such as, for example vapor deposition, plasma-enhanced chemical vapor deposition, spin on coating, or other like processes.

Hard mask 140 is formed atop dielectric layer 130. In a case where dielectric layer 130 is an oxide, hard mask 140 could be, for example, silicon nitride or another material that has a high degree of resistance to etchants typically employed to etch oxides. Other materials, such as SiCN, SiOC, and the like could also be employed for hard mask 140.

Mask 150 is formed atop hard mask 140. In the illustrated embodiment, mask 150 is a tri-layer mask comprising three separate layers. While a conventional mask layer, such as a single polymer photoresist layer, could be employed, a tri-layer mask 150 allows for the formation of finer features having smaller dimensions and pitch. In the illustrated embodiment, bottom layer 160 of tri-layer mask 150 is a carbon organic layer, similar to a conventional photoresist layer. Middle layer 170 is a silicon containing carbon film, employed to help pattern bottom layer 160. Top layer 180 is a photoresist material, such as for instance, a photoresist material designed for exposure to 193 nm wavelengths, and preferably designed for immersion photolithography, for instance.

As shown in FIG. 4, an opening 190 is formed in mask 150, using known lithography techniques, such as for instance, immersion photolithography. This opening will be transferred to all layers of mask 150, through hard mask 140 and then to dielectric layer 130 and etch stop layer 120, resulting in an opening 195, sometimes referred to herein as a via opening, being formed in dielectric layer 130 and etch stop layer 120, as shown in FIG. 5. Note that opening 195 exposes an underlying portion of substrate 110 which, as described above, could be an underlying conductive interconnect, a transistor contact, or the like. Mask 150 is removed using known ashing and/or etching techniques, the details of which are omitted herein.

Turning now to FIG. 6, a metal layer 200 is deposited over semiconductor structure 100, the metal layer 200 having a first etch rate. In illustrated embodiments, a material of the metal layer 200 is a copper alloy. Examples of a suitable copper alloy include CuMn, CuCr, CuV, CuNb, and CuTi. The copper alloy may be in the range of from about 90% copper to about 99.8% copper. Other suitable alloys and percentages will be apparent to those skilled in the art upon undertaking routine experimentation once informed by the present disclosure. By using a copper alloy material, it is possible to manufacture copper interconnects without the need to form barrier lines, such as Ta, TaN, and the like, that are commonly employed in conventional damascene processes. That being said, it is within the contemplated scope of the present invention that a barrier liner could be employed in some applications.

In one embodiment, metal layer 200 is formed by a plasma vapor deposition (PVD) that completely fills opening 195 and forms a blanket coating over a top surface of dielectric layer 130, or more accurately over the top surface of hard mask 140 overlying dielectric layer 130. In some embodiments, hard mask 140 may be omitted, in which case metal layer 200 would be formed on dielectric layer 130. Metal layer 200 may be formed to a thickness above dielectric layer 130 of from about 500 A to about 2 um, depending upon the desired application and the technology node employed.

In another embodiment, metal layer 200 is formed by first depositing a seed layer by, e.g., physical vapor deposition techniques. The seed layer could be formed to a thickness of perhaps about 20 A to about 100 A, although other thicknesses could be employed depending upon the application and the desired process. Then a copper alloy material is formed on the seed layer using, e.g., an electro-plating or electro-less plating technique.

The metal layer 200 is planarized by a chemical mechanical polishing (CMP) or an etch back step, for example to form a metal feature 201 whose top is substantially co-planar with a top surface of the hard mask layer 140, as illustrated in FIG. 7. Also shown in FIG. 7, in an aspect of the present disclosure, an anneal or heat process 210 is applied to the semiconductor structure 100 to control the etch rate of the copper alloy in the metal feature 201. The etch rate of the copper alloy in the metal feature 201 is changed from the first etch rate to a second etch rate, the second etch rate being lower than the first etch rate. The anneal process 210 may be a rapid thermal anneal (RTA), a laser anneal, and/or a flash lamp anneal. The anneal process may be conducted in an oxygen ambient, a combination of steam ambient and oxygen ambient combined, or under an inert gas atmosphere. The annealing may be performed in a single wafer rapid thermal annealing (RTP) system or a batch type furnace system or the anneal procedure can be performed in situ in the same tool. In an exemplary embodiment, the semiconductor structure 100 is placed in an inert environment, such as 95% H2, 5% N2 and annealed at a temperature of from about room temperature to about 400 C for a time period of from about 1 minute to about 180 minutes, for example. As a result of the annealing, the copper alloy in the metal feature 201 is densified so that an etching rate of the annealed metal feature 201 is significantly reduced to be less than or equal to about 80-85 percent of an etching rate of the metal feature 201 before being annealed. The annealing can be tailored to achieve the desired etching rate. FIG. 11 is a chart showing different etch rates of copper alloy versus pure copper at different annealing conditions. This will be discussed in further detail below but as can be seen from FIG. 11, the copper alloy in the metal layer 200 or the metal feature 201 has an etching rate of about 60.0 A/min before annealing. However, when the copper alloy is annealed at a temperature of about 180 C, the copper alloy is densified so that the etching rate is reduced to about 52 A/min. At an annealing temperature of 300 C for about 90 seconds, the etching rate of the copper alloy is further reduced to about 42 A/min. When the copper alloy is annealed at a temperature of about 400 C, the copper alloy is further densified so that the etching rate is reduced further still to about 38 A/min.

Referring now to FIG. 8, a copper containing layer 220 is deposited over the annealed metal feature 201 and the hard mask 140. In an exemplary embodiment, the copper containing layer 220 has from about 98% to about 100% copper and has an etch rate greater than the etch rate of the copper alloy in the annealed metal layer 200. The copper containing layer 220 may be deposited by plasma vapor deposition (PVD), for example. The copper containing layer 220 is thereafter thinned down (e.g., via chemical mechanical polish, CMP, by etch back, or the like).

Although not shown in FIG. 8, an etch stop layer may be formed on the planarized copper containing layer 220. In one embodiment, the etch stop layer is formed of silicon nitride, silicon carbon nitride, or another material that provides sufficient etch selectivity relative to the copper containing layer 220.

Turning now to FIG. 9, a second mask 230 is formed. In the illustrated example, mask 230 is a tri-layer mask similar to mask 150 illustrated in FIG. 4. As with the previously described steps, it is not necessary to use a tri-layer mask, unless the particular application and feature size calls for such an approach. Regardless of the type of mask employed, a pattern is formed in mask 230 as shown in FIG. 9. Next, as shown in FIG. 10, the pattern is transferred to copper containing layer 220 using known lithography techniques. Copper containing layer 220 is preferably etched anisotropically to form nearly vertical sidewalls. In some embodiments, a chlorine plasma etch is employed to pattern copper containing layer 220. Other plasma etches, including reactive ion etching (RIE), could also be employed.

The result of the etching step is that the copper containing layer 220 is patterned into interconnect features or interconnects 280. These interconnect features 280 run across the major surface of semiconductor structure 100 and may be metal lines, metal vias, or via features to provide vertical electrical routing between metal lines. The etching stops at the annealed metal feature 201 and does not etch thereunder, thus avoiding undesirable recesses that may be formed in the prior art method and resulting in a recess free (RF) semiconductor structure 100. The faster etching rate of the copper containing layer 220 is desirable because it eliminates or reduces the amount of undercutting that will occur in the annealed metal feature 201. As can be seen from FIG. 10, there is little or no undercutting of the annealed metal feature 201.

A reason that the etching can be accurately terminated at the top surface annealed metal feature 201 and not etch thereunder is that the etch rate of the copper alloy in the annealed metal feature 201 can be controlled, as discussed above. FIG. 11 is a chart showing different etch rates of copper alloy versus pure copper at different annealing conditions. The chart shows that the etching rate of pure copper of the copper containing layer 220 etches at a faster rate when compared to the copper alloy in the metal feature 201. Put another way, the etching selectivity of the copper containing layer 220 is higher relative to the metal layer 200 after annealing. In one aspect, the etching selectivity of the copper containing layer 220 relative to the metal layer 200 after annealing is at least 5:1. According to FIG. 11, at an annealing temperature of 180 Celsius for a time period of about 90 seconds, the etch rate of pure copper is about 85 A/min, whereas the etch rate of copper alloy is slower at about 52 A/min. And at an annealing temperature of 400 Celsius for a period of about 2 hours, the etch rate of pure copper is about 100 A/min, whereas the etch rate of copper alloy is even slower at about 38 A/min. So by controlling the annealing temperature and time, the etch rate of copper metal can be controlled, in turn accurately controlling its etch rate.

Further processing steps could include depositing a dielectric layer in the openings between the interconnect features 280 and planarizing the dielectric layer. The above described process steps may be repeated for the formation of additional vertical and horizontal interconnect features.

Although the present embodiments and their advantages have been described in detail, it should be understood that various changes, substitutions and alterations can be made herein without departing from the scope of the disclosure as defined by the appended claims.

The present disclosure has described various exemplary embodiments. According to one embodiment, a method for forming a semiconductor interconnect structure comprises forming a dielectric layer on a substrate and patterning the dielectric layer to form an opening therein. The opening is filled and the dielectric layer is covered with a metal layer having a first etch rate. The metal layer is thereafter planarized so that the metal layer is co-planar with the top of the dielectric layer. The metal layer is then annealed to change the first etch rate into a second etch rate, the second etch rate being lower than the first etch rate. A copper-containing layer is formed over the annealed metal layer and the dielectric layer, wherein the copper-containing layer has an etch rate greater than the second etch rate of the annealed metal layer. The copper-containing layer is etched to form interconnect features, wherein the etching stops at the top of the annealed metal layer and does not etch thereunder.

According to another embodiment, a method for forming an integrated circuit interconnect structure comprises forming a via opening in a dielectric layer. The via opening is filled and the dielectric layer is covered with a copper alloy layer having a first etch rate. The copper alloy layer is planarized so that the copper alloy layer is co-planar with the top of the dielectric layer. The copper alloy layer is thereafter annealed. A copper-containing layer is formed over the annealed copper alloy layer and the dielectric layer. The copper-containing layer has an etch selectivity higher than the annealed copper alloy layer. The copper-containing layer is etched to form interconnect features, wherein the etching stops at the top of the annealed copper alloy layer and does not etch therein.

According to yet another embodiment, an integrated circuit interconnect structure comprises a dielectric layer on a substrate. A copper alloy feature extends substantially vertically into the dielectric layer, the copper alloy feature having a first etch rate. A plurality of copper containing interconnect features on the dielectric layer and the copper alloy feature, wherein the copper containing interconnect features comprise from about 98% to about 100% copper and have a second etch rate, the second etch rate being greater than the first etch rate.

In the preceding detailed description, specific exemplary embodiments have been described. It will, however, be apparent to a person of ordinary skill in the art that various modifications, structures, processes, and changes may be made thereto without departing from the broader spirit and scope of the present disclosure. The specification and drawings are, accordingly, to be regarded as illustrative and not restrictive. It is understood that embodiments of the present disclosure are capable of using various other combinations and environments and are capable of changes or modifications within the scope of the claims. 

What is claimed is:
 1. A method of manufacturing a semiconductor interconnect structure, the method comprising: forming a low-k dielectric layer over a substrate; forming an opening in the low-k dielectric layer, the opening exposing a portion of the substrate; filling the opening with a copper alloy; forming a copper-containing layer over the copper alloy and the low-k dielectric layer, wherein an etch rate of the copper-containing layer is greater than an etch rate of the copper alloy; and patterning the copper-containing layer to form interconnect features over the low-k dielectric layer and the copper alloy.
 2. The method of claim 1, wherein the etch rate of the copper-containing layer is in a range from about 80 Angstroms per minute to about 110 Angstroms per minute, and wherein the etch rate of the copper alloy is in a range from about 38 Angstroms per minute to about 52 Angstroms per minute.
 3. The method of claim 1, further comprising annealing the copper alloy prior to forming the copper-containing layer.
 4. The method of claim 3, wherein the annealing comprises annealing at a temperature of about 180 degrees Celsius for a duration of about 90 seconds.
 5. The method of claim 3, wherein the annealing comprises annealing at a temperature of about 300 degrees Celsius for a duration of about 90 seconds.
 6. The method of claim 3, wherein the annealing comprises annealing at a temperature of about 400 degrees Celsius for a duration of about 2 hours.
 7. The method of claim 1, wherein the low-k dielectric layer has a dielectric constant less than about 3.5.
 8. The method of claim 1, wherein the copper alloy comprises from about 90% copper to about 99.8% copper, and wherein the copper-containing layer comprises from about 98% copper to about 100% copper.
 9. The method of claim 1, wherein the copper alloy comprises a material selected from the group consisting essentially of CuMn, CuCr, CuV, CuNb, CuTi, and combinations thereof.
 10. The method of claim 1, wherein the forming the opening in the low-k dielectric layer comprises: forming a tri-layer mask over the substrate, the tri-layer mask comprising a carbon organic layer, a silicon-containing carbon film disposed over the carbon organic layer, and a photoresist layer disposed over the silicon-containing carbon film; forming a trench extending through each of the photoresist layer, the silicon-containing carbon film, and the carbon organic layer; and extending the trench into the low-k dielectric layer to form the opening using the photoresist layer, the silicon-containing carbon film, and the carbon organic layer as a mask.
 11. A method of manufacturing a semiconductor interconnect structure, the method comprising: depositing a dielectric layer over a substrate; forming a hard mask over the dielectric layer; forming an opening in the hard mask; extending the opening into the dielectric layer to expose a surface of the substrate; forming a copper alloy feature in the opening extending through the hard mask and the dielectric layer; annealing the copper alloy feature, the annealing causing an etch rate of the copper alloy feature to be in a range from about 38 Angstroms per minute to about 52 Angstroms per minute; after the annealing, depositing a copper-containing layer over the copper alloy feature and the hard mask; and etching the copper-containing layer to form interconnect features, wherein the etching terminates at a top surface of the copper alloy feature.
 12. The method of claim 11, wherein the annealing comprises placing the copper alloy feature, the dielectric layer, the hard mask, and the substrate in an environment comprising 95% H2 and 5% N2, and annealing at a temperature from about room temperature to about 400 degrees Celsius for a duration from about 1 minute to about 180 minute.
 13. The method of claim 11, the annealing comprises: selecting a desired etch rate of the copper alloy feature, the desired etch rate being in the range from about 38 Angstroms per minute to about 52 Angstroms per minute; determining a temperature and a duration of the annealing based on the desired etch rate of the copper alloy feature; and conducting the annealing at the determined temperature for the determined duration.
 14. The method of claim 11, wherein the annealing comprises at least one of a rapid thermal anneal, a laser anneal, or a flash lamp anneal.
 15. The method of claim 11, wherein the annealing is conducted in an oxygen ambient, a combination of steam ambient and oxygen ambient, or an inert gas environment.
 16. The method of claim 11, wherein the hard mask comprises a material selected from the group consisting essentially of silicon nitride, SiCN, SiOC, and combinations thereof.
 17. A method comprising: patterning an opening in a dielectric layer; filling the opening with a first conductive material; annealing the first conductive material, wherein annealing the first conductive material comprises controlling one or more process conditions during annealing the first conductive material in accordance with a desired etch rate of the first conductive material after annealing; after annealing the first conductive material, forming a second conductive material over the first conductive material and the dielectric layer; and patterning the second conductive material to form interconnect features over the dielectric layer.
 18. The method of claim 17, wherein the first conductive material comprises a first etch rate during patterning the second conductive material, and wherein the second conductive material comprises a second etch rate greater than the first etch rate during patterning the second conductive material.
 19. The method of claim 17, wherein the one or more process conditions comprises annealing temperature, annealing time, or a combination thereof.
 20. The method of claim 17, wherein the first conductive material comprises a copper alloy, and wherein the second conductive material comprises substantially pure copper. 